(E)-4-Bromo-N′-(4-hydroxy-3-methoxybenzylidene)benzohydrazide monohydrate
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چکیده
In the title compound, C(15)H(13)BrN(2)O(3)·H(2)O, the dihedral angle between the two benzene rings is 13.92 (6)°. The meth-oxy group of the 4-hy-droxy-3-meth-oxy-phenyl is almost coplanar with its bound benzene ring, as seen by the C(meth-yl)-O-C-C torsion angle of -0.35 (16)°. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds and also weak C-H⋯O inter-actions. A short C⋯O contact of 3.0191 (15) Å is also present.
منابع مشابه
(E)-N′-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-2-hydroxybenzohydrazide monohydrate
The organic molecule of the title hydrate, C(15)H(13)BrN(2)O(4)·H(2)O, is roughly planar, with a mean deviation of 0.0939 (2) Å. The dihedral angle between the two aromatic rings is 8.2 (3)°. Intra-molecular O-H⋯N and O-H⋯O hydrogen bonds are observed. In the crystal, N-H⋯O(water) and O(water)-H⋯O hydrogen bonds lead to a three-dimensional network.
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The title compound, C15H13BrN2O3·H2O, exists in an E conformation with respect to the azo-methane C=N double bond. The benzene and phenyl rings form dihedral angles of 0.46 (2) and 4.90 (3)°, respectively with the central C(=O)N2C unit. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal, some hydrazide mol-ecules are replaced by mol-ecules of the 6-bromo isomer. The Br atom from this...
متن کامل(E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate
In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base mol-ecule shows an E conformation around the C=N bond. An intra-molecular O-H⋯N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40 (11)°. The water mol-ecule mediates linking of neighbouring mol-ecules through O-H⋯(O,O) hydrogen bonds into infinite chains along the a a...
متن کامل(E)-4-Hydroxy-N′-(4-hydroxy-3-methoxybenzylidene)benzohydrazide
In the title compound, C(15)H(14)N(2)O(4), the N=C double bond has an E configuration. The two benzene rings make a dihedral angle of 28.59 (6)°. In the crystal, mol-ecules are linked into a three-dimensional network by inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds and stabilized by weak C-H⋯π inter-actions.
متن کامل(E)-4-Hydroxy-N′-(3-hydroxy-4-methoxybenzylidene)benzohydrazide
The mol-ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17 (6)°. The meth-oxy group is almost co-planar with respect to the attached benzene ring [C(m)-O-C-C (m = meth-yl) = -1.45 (17)°]. In the crystal, the mol-ecules are linked by N-H⋯O...
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